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Cryogenic Information Library
Nitrogen - Cryogenic Fluids

Nitrogen (N), when cooled, condenses at -320.42°F (-195.8°C or 77.36 K) and freezes at -345.9°F (-209.86°C or 63.17 K).  Or, to reverse the order, solid nitrogen melts to form liquid nitrogen at -345.9°F, which boils at -320.42°F  Liquid nitrogen is used in a wide range of cryogenic applications.

The Scottish physician Daniel Rutherford discovered nitrogen in 1772.  It is the fifth most abundant element in the universe and makes up about 78% of the earth's atmosphere, which contains an estimated 4,000 trillion tons of the gas.  Nitrogen is obtained from liquefied air through a process known as fractional distillation.

The largest use of nitrogen is for the production of ammonia (NH3).  Large amounts of nitrogen are combined with hydrogen to produce ammonia in a method known as the Haber process.  Large amounts of ammonia are then used to create fertilizers, explosives and, through a process known as the Ostwald process, nitric acid (HNO3).

Nitrogen gas is largely inert and is used as a protective shield in the semiconductor industry and during certain types of welding and soldering operations.  Oil companies use high-pressure nitrogen to help force crude oil to the surface.  Liquid nitrogen is an inexpensive cryogenic liquid used for refrigeration, preservation of biological samples and for low temperature scientific experimentation.

Atomic Number 7
Atomic Weight 14.0067
Melting Point 63.15 K
Boiling Point 77.36 K
Heat of Vaporization 198.3 kj/kg K
Specific Heat 2.04 kj/kg K
Viscosity 157.9 kg/m-s X 106
Thermal Conductivity 139.6 mW/m-k
Dielectric Constant 1.434
Critical Temperature 126.2K
Critical Pressure 3.399 MPa
Temperature at Triple Point 63.148 K
Pressure at Triple Point 12.53 Mpa X 103
Density .0012506 grams/cc
Phase at Room Temperature Gas


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