About Liquid Nitrogen

Nitrogen (N2), when cooled, condenses at -320.4°F (-195.8°C or 77.36 K) and freezes at -345.9°F (-209.8°C or 63.17 K). Or, to reverse the order, solid nitrogen melts to form liquid nitrogen at -345.9°F, which boils at -320.4°F Liquid nitrogen is used in a wide range of cryogenic applications.

The Scottish physician Daniel Rutherford discovered nitrogen in 1772. It is the fifth most abundant element in the universe and makes up about 78% of the earth's atmosphere, which contains an estimated 4,000 trillion tons of the gas. Nitrogen is obtained from liquefied air through a process known as fractional distillation.

The largest use of nitrogen is for the production of ammonia (NH3). Large amounts of nitrogen are combined with hydrogen to produce ammonia in a method known as the Haber process. Large amounts of ammonia are then used to create fertilizers, explosives and, through a process known as the Ostwald process, nitric acid (HNO3).

Nitrogen gas is largely inert and is used as a protective shield in the semiconductor industry and during certain types of welding and soldering operations. Oil companies use high-pressure nitrogen to help force crude oil to the surface. Liquid nitrogen is an inexpensive cryogenic liquid used for refrigeration, preservation of biological samples and for low temperature scientific experimentation.

Property Value

Symbol

N2

Melting Point

63.15 K

Boiling Point

77.36 K

Heat of Vaporization (@101.325 kPa)

198.3 kj/kg K

Specific Heat (Cp, 0°C @ 101.325 kPa)

2.04 kj/kg K

Viscosity

157.9 kg/m-s X 106

Thermal Conductivity (k)

139.6 mW/m-k

Critical Temperature

126.2 K

Critical Pressure

3.399 MPa

Temperature at Triple Point

63.148 K @ 12,530 MPa

Saturated Liquid Density (p) @ 0°C, 101.325 kPa

808.6 kg/m3

Phase at Room Temperature (20°C)

Gas


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Cryogenic Society of America